Performance Comparison of a Self-Cleaning and a Conventional pH Electrode in Wastewater Process Monitoring

Abraham de Guzman, Elyson Keith Encarnacion
Abstract:
Accurate pH measurement is vital in wastewater treatment for effective process control and regulatory compliance. This study compares a self-cleaning pH sensor (HORIBA 6122 series) with a conventional glass electrode, installed in parallel at a wastewater treatment facility in Metro Manila, Philippines. Over a 97-day period, 2,324 paired readings were recorded. Statistical analysis revealed a significant difference (t(2323) = 56.88, p > 0.05) in mean values (HORIBA = 6.93, conventional = 6.12). The HORIBA sensor exhibited lower variability (HORIBA = 0.2335, conventional = 0.6461) through time, indicating better stability. These results align with the goals of Process Analytical Technology and support the deployment of self-cleaning sensors for real-time wastewater treatment monitoring.
Download:
IMEKO-TC8-11-24-2025-042.pdf
DOI:
10.21014/tc24-2025.042
Event details
IMEKO TC:
TC24
Event name:
IMEKO TC8, TC11 and TC24 Conference
Title:

Joint conference of the TCs ‘Traceability in Metrology’ (IMEKO TC8), ‘Measurement in Testing, Inspection and Certification’ (IMEKO TC11), and ‘Chemical Measurements’ (IMEKO TC24).

Place:
Torino, ITALY
Time:
14 September 2025 - 17 September 2025